Watercalcs
Estimates only — verify before relying on results. Terms of Use
v2.1
Guide — source quality

Enter the source water analysis. Everything downstream in the tool runs from these numbers.

  • Unit basis. Nitrate is reported on two bases. As nitrate-nitrogen (NO₃-N) or as the nitrate ion (NO₃). They differ by a factor of 4.427 and describe the same water. New Zealand laboratories usually report NO₃-N. The Drinking Water Standards set the limit as the ion. The toggle below switches every figure in the tool, including the reference lines. It changes nothing physical.
  • Redox is the diagnostic. Nitrate persists in oxic groundwater and is denitrified naturally in reducing groundwater. Dissolved iron and manganese with low oxygen and low nitrate is the signature of an aquifer that is already destroying nitrate for you — and of an aquifer that will hand you iron, manganese, ammoniacal nitrogen and, in some settings, arsenic instead.
  • Why this matters before you look at treatment. The obvious response to a nitrate exceedance is a deeper bore into a confined, reduced aquifer. That is sometimes the right answer. It is not a clean answer, and the panel below names what you would inherit.
  • Sulfate, alkalinity and chloride are not optional. They set ion exchange run length, the chromatographic peak, and the chloride-to-sulfate mass ratio in the product water.
New to this tool? Load a worked example. It fills every tab with a realistic groundwater supply — a bore that is compliant today but committed to an exceedance — so you can see how the tool works before entering your own data. Toggle it off to clear it and start fresh.

Unit basis

Supply and source

Nitrogen species

Redox indicators

Optional. Advisory only.
Optional. If known.

Major ions

Optional. Estimated if blank.

Existing treatment on this plant

Tick every process currently installed. The tool reports what each one does to nitrate.

Redox interpretation

Enter dissolved oxygen, iron, manganese and nitrate to classify the aquifer.

Anion balance

Sets ion exchange behaviour
Enter nitrate, sulfate, chloride and alkalinity.
Guide — compliance and risk
  • The nitrate MAV is a short-term value. It was set to protect bottle-fed infants against methaemoglobinaemia. There is no averaging, no percentile and no transgression allowance. A single result above the MAV is an exceedance and the response is immediate.
  • Nitrate and nitrite are assessed together. Each is measured against its own MAV and the two ratios are summed. The sum must not exceed 1. Water can be below both individual MAVs and still fail.
  • Two of the treatment options in this tool make nitrite. Ion exchange run past breakthrough, and biological denitrification with an inadequate carbon dose. The sum-of-ratios rule is the reason that matters.
  • The monitoring engine reads the rules level and the source class and returns the applicable DWQAR 2026 rule, the frequency, and what escalates it. Enter the last twelve months of results as counts and it will also test the step-down conditions.
  • The risk panel returns no verdict. It places the water against reference lines of three different kinds — legal, advisory and research — and states what each one is. Read the About panel section “What this evidence does and does not establish” before any of this goes into a document that reaches a community.

Standards comparison

DWSNZ 2022
Enter nitrate on the Source Quality tab.

Monitoring rules

DWQAR 2026

Bottle-fed infant exposure

Intake is already per kg, so the result is independent of the infant’s weight.
Reconstituted entirely with this water.

This water against the reference lines

No verdict
Enter nitrate on the Source Quality tab.

Source term

In the New Zealand aquifers where drinking water nitrate is elevated, the dominant nitrogen source is leaching from intensive pastoral land use in the catchment. That is a statement of hydrology and mass balance. This tool takes no position on land use, and none of the reference lines above should be read as one.

Guide — catchment lag
  • The bore is not drinking today’s rain. It is drinking water that entered the ground years to decades ago, carrying the nitrogen that was leaching then. A change in land use today does not appear at the bore today. It appears over the residence time of the aquifer.
  • Loading already in transit. If the nitrate in recharge entering the aquifer now is higher than the nitrate at the bore, then the bore is still rising and it will keep rising even if nothing in the catchment changes. That is the committed load. A supply can be compliant today and already be committed to an exceedance, and no treatment decision made on today’s number will be the right size.
  • It runs both ways. An intensification and a reduction obey the same time constant. The scenarios below cover both, because a supply needs to know what a worsening catchment does to it as much as what an improving one does.
  • Two separate questions, and conflating them is where the argument goes wrong. How much the loading has to change is set by the steady state, and it does not depend on the residence time at all. How long it takes to arrive is set by the residence time, and it does not depend on how much. The tool answers them in separate panels for that reason.
  • The model is an idealisation and its assumptions are printed at the bottom of this tab. The mean residence time is rarely known better than a factor of two, and every time in the output scales with it.

The aquifer

How fast the bore responds
Well-mixed suits most bores. Pick “mixed, with a delay” to set a travel delay below.
From tritium, CFC or SF₆ dating.
Share of the water age spent as a straight travel delay before the aquifer mixes. 0 responds at once; 0.9 waits, then changes sharply.
Time through the unsaturated zone.

The catchment

What is arriving, and what you are testing
Under today’s land use. Blank = bore is steady.
The floor. Loading cannot go below it.
How far the chart projects.

Scenario to highlight. Pick a change in catchment nitrogen loading and the tool shows what it does to the bore. The table below always shows the full range either way.

Minus improves, plus worsens.

Committed load

What the bore does if nothing in the catchment changes
Enter nitrate on the Source Quality tab and a mean residence time above.

How much the loading must change

Independent of the residence time

Improving and worsening scenarios

How long, given the residence time

Assumptions

Guide — ion exchange
  • Resin choice is the whole design. A conventional strong base anion resin prefers sulfate to nitrate. A nitrate-selective resin (tributylamine or triethylamine functionality) reverses that preference at the cost of some capacity. On the same water the run lengths differ by an order of magnitude.
  • Chromatographic peaking. On a sulfate-selective resin, nitrate breaks through first and is then displaced off the resin by the advancing sulfate front. The effluent nitrate rises above the feed concentration until sulfate breaks through. Against a short-term MAV that is an acute exceedance. On a nitrate-selective resin the preference is reversed, nitrate leaves last, and there is no peak.
  • Partial treatment saves money. The treated water leaves the column at essentially zero nitrate, so you rarely need to treat all of it. Send a fraction through the resin, bypass the rest of the same bore around it, and recombine to hit your target. A smaller plant, less salt, less waste. The panel below tells you the smallest fraction that still meets the MAV.
  • The product water is a different water. Chloride-form resin exchanges chloride for nitrate, sulfate and bicarbonate. Chloride rises, sulfate falls, alkalinity falls, pH falls. The chloride-to-sulfate mass ratio rises, and a rising CSMR is a recognised driver of lead and copper release from plumbing. This is how a nitrate fix creates a lead problem.
  • The nitrogen goes into the brine. It is not destroyed. The kg N/day figure below is the number to take to whoever owns the disposal route.

How much to treat

Treat a fraction, bypass the rest of this bore
Bypass is raw water from this same bore.
The rest bypasses and recombines.
Defaults to the MAV. Sets the minimum fraction.

Coverage and blended product

Resin and vessel design

Nitrate-selective avoids the peak.
Lead–lag catches a peak.
Typical 1.5 to 3 minutes.
 
 
Regenerant.
 

Run length and vessel sizing

Enter nitrate, sulfate, chloride and alkalinity on the Source Quality tab.

Chromatographic peaking

Product water chemistry

Regeneration and waste

Guide — reverse osmosis
  • Nitrate is rejected less well than most ions. It is small, monovalent and weakly hydrated. Typical observed rejection is 85 to 95%, not the 98 to 99% that a membrane datasheet shows for sulfate and hardness. Sizing an RO plant on the datasheet salt rejection will undersize it for nitrate. The default here is 90% and it is editable in Settings.
  • Partial treatment saves money. Permeate is near-zero nitrate, so you rarely treat all the flow. Send a fraction through the membranes, bypass the rest of the same bore around them, and recombine. Bypassing raw water also restores some hardness and alkalinity, which reduces the remineralisation duty. The panel below gives the smallest fraction that still meets the MAV.
  • Permeate is aggressive. Near-zero alkalinity and hardness, strongly negative LSI. Remineralisation is not a finishing touch, it is part of the process, and the tool will not report a compliant design without it.
  • The concentrate is the design constraint at an inland site. The nitrogen is not destroyed, it is concentrated. The kg N/day figure below is what has to go somewhere. If that somewhere is land or a soakage field in the same catchment, the nitrogen returns to the aquifer.

How much to treat

Treat a fraction, bypass the rest of this bore
Bypass is raw water from this same bore.
The rest bypasses and recombines.
Defaults to the MAV. Sets the minimum fraction.

Coverage and blended product

Membrane design

Permeate as a share of RO feed.
 
 
Applied to the permeate stream.

Flows and product quality

Enter nitrate and a design flow on the Source Quality tab.

Rejection by ion

Post-treatment

Concentrate

Guide — options and comparison
  • Every option is modelled independently against the source water on the Source Quality tab, using the configuration set on each design tab.
  • The nitrogen fate column is the one that is easy to skip and should not be. Ion exchange and reverse osmosis produce compliant water and a concentrated nitrogen waste stream. They do not destroy nitrogen. At an inland site with no marine outfall, the waste stream usually returns to land, to ground, and to the aquifer.
  • Two things here look similar and are not the same. On the Ion Exchange and Reverse Osmosis tabs, partial treatment treats a fraction of this bore and bypasses the rest of the same bore. Blending below mixes in a different source that already has lower nitrate. Both are weighted averages, which is why they feel alike, but one needs a treatment plant and the other needs a second bore.
  • Cost bands are indicative and relative. Use the cost estimation tool for a CAPEX/OPEX/NPV comparison.

Target

Defaults to the MAV.
 

Blending with a different source

A second bore or supply that already has lower nitrate, mixed in to bring the combined water down. Leave blank if there is none. This is not the same as partial treatment on the Ion Exchange and Reverse Osmosis tabs: blending removes no nitrogen and depends entirely on the other source staying available.

What your existing plant does to nitrate

Option comparison

Enter nitrate and a design flow on the Source Quality tab.

Nitrogen mass balance

Diagnostics

Guide — report and save

This is the only export point in the tool. Select the sections to include, then print to PDF, export the results to CSV, or save the full input state as JSON for reload later.

Report sections

 
 

Summary

Enter source water on the Source Quality tab.